This Source is a self-reference.
It represents the database and the query that produced the xml document.
The sourceID contains a timestamp.
The full URL is given in the tag UniformResourceIdentifier but you need
to unescape ampersands and angle brackets to re-use it.
Query was: SELECT ALL WHERE MoleculeStoichiometricFormula = 'C7H7NO2'
Query Store Link: https://querystore.vamdc.eu/GetUUIDByToken?queryToken=IDEADB:e8307c40-0d64-49e7-9b81-bdfabac559d8:get
2026databasehttps://ideadb.uibk.ac.at/tap/sync?FORMAT=XSAMS&LANG=VSS2&QUERY=SELECT+ALL+WHERE+MoleculeStoichiometricFormula+%3D+%27C7H7NO2%272026-04-20N.N.
Denifl, Stephan
Matejcik, Stefan
Probst, Michael
Scheier, Paul
Märk, Tilmann
Ptasinska, Sylwia
Mauracher, Andreas
Sulzer, Philipp
Bacher, Arntraud
Zappa, Fabio
Beikircher, Manuel
Wendt, Nina
Aleem, Abid
Rondino, F
Identification of Isomers of Nitrotoluene via Free Electron Attachment
journal
20077965856591http://pubs.acs.org/doi/abs/10.1021/ac070656b10.1021/ac070656b
C7H7NO2C7H7NO2
-12-Nitrotoluene
88-72-2
137.13598
C7H6NO2C7H6NO2
-1
136.12804
C7H6NOC7H6NO
-1
120.12863999999999
C7H5NOC7H5NO
-1
119.12069999999999
C7H7OC7H7O
-1
107.12988
C7H6OC7H6O
-1
106.12194
C7H7C7H7
-1
91.13048
C6H5C6H5
-1
77.1039
C7H7NO2C7H7NO2
-13-Nitrotoluene
99-08-1
137.13598
C7H7NO2C7H7NO2
-14-Nitrotoluene
99-99-0
137.13598
C7H4C7H4
-1
88.10666
low energy electrons-1
Comment of the Producer: Ion efficiency curves for the parent negative ions of the three mono-nitrotoluene isomers (m/z=137). Additional Comment: X-Values are measured with an energy resolution of 0.080 eV. Therefore every shown peak is the original peak shape convoluted with our resolution. Energy scans are calibrated. Therefore we estimate an error of 0.1 eVBIDEADB-13elatEDAXIDEADB-109XIDEADB-electronXIDEADB-109Energy of the impact electron0.1Ion Yield347.81 302.75 295.41 247.09 209.50 182.28 168.33 136.22 137.26 119.54 105.07 93.04 82.90 69.86 68.57 60.51 52.01 44.66 36.77 32.81 30.56 25.60 23.00 20.35 17.75 17.22 16.89 14.55 15.76 11.94 12.32 12.60 11.55 11.35 10.29 9.10 10.51 9.83 9.10 9.71 9.83 10.72 11.25 10.72 10.83 10.40 8.97 10.51 9.22 9.22 8.97 9.10 9.35 9.47 8.58 9.10 9.59 8.71 9.47 8.58 9.83 7.73 8.84 6.95 7.88 9.10 8.17 7.58 7.73 8.17 7.27 6.78 8.58 8.02 7.11 7.11 7.43 7.43 7.58 7.58 6.61 5.67 6.95 6.78 6.78 6.07 6.78 7.58 6.25 6.78 6.43 6.78 5.47 5.47 6.25 5.47 6.07 7.43 6.78 6.78 6.25 6.07 5.03 5.03 5.87 5.25 5.25 6.25 6.07 5.25 6.25 6.07 5.67 6.07 6.95 4.29 5.25 4.80 6.95 5.25 5.25 4.55 5.03 6.07 5.67 5.03 4.80 5.25 5.03 4.80 5.03 3.39 5.03 3.71 5.87 5.67 5.25 6.25 4.29 4.55 5.25 4.80 5.25 4.80 4.80 6.07 5.47 5.67 4.01 5.03 5.47 5.03 5.87 4.55 4.80 5.03 5.03 4.29 4.80 5.87 4.01 4.55 3.03 4.80 3.392007-09-01Comment of the Producer: Ion efficiency curves for the closed shell negative ions (M-H)– formed via loss of a neutral hydrogen atom for the three isomers of mono-nitrotoluene. All anion yields are measured with the monochromator instrument. Additional Comment: X-Values are measured with an energy resolution of 0.080 eV. Therefore every shown peak is the original peak shape convoluted with our resolution. Energy scans are calibrated. Therefore we estimate an error of 0.1 eVBIDEADB-13elatEDAXIDEADB-109XIDEADB-electronXIDEADB-112Energy of the impact electron0.1Ion Yield9.24 7.54 5.58 3.47 2.84 1.43 0.92 0.85 0.49 0.85 0.85 0.35 0.60 0.49 0.60 0.69 0.85 0.60 0.85 0.78 0.85 1.20 1.04 1.10 0.92 1.10 1.20 1.10 1.25 1.51 1.25 1.20 1.10 1.04 0.85 0.92 0.98 1.04 0.98 0.92 0.69 1.04 0.92 0.92 0.85 0.69 0.78 0.60 1.39 1.25 0.98 1.39 1.55 1.74 2.08 2.40 2.84 3.51 3.52 4.03 4.87 5.17 5.41 6.42 6.95 7.18 7.80 8.50 8.47 9.15 9.42 9.77 10.07 10.52 10.88 11.17 11.41 11.47 12.02 11.57 11.50 11.33 11.18 10.56 10.82 10.05 9.22 8.82 8.45 7.76 7.48 6.93 6.47 5.67 5.30 5.16 4.45 4.57 4.03 3.57 3.62 3.20 2.86 2.76 2.60 2.73 2.38 2.35 2.11 2.22 2.30 2.05 1.66 1.90 1.43 1.77 1.77 1.63 1.10 1.39 1.51 1.39 1.59 1.63 1.74 1.47 1.47 1.39 1.25 1.47 1.04 1.80 1.25 1.25 1.74 1.93 1.84 2.33 2.73 2.71 3.05 3.14 3.42 3.82 4.43 4.59 4.87 5.32 5.55 5.77 5.94 6.32 6.48 6.57 6.69 6.61 6.62 7.03 6.29 5.98 6.50 5.76 5.68 5.47 5.07 5.02 4.66 4.19 4.19 4.19 4.02 3.40 3.54 3.18 3.01 3.22 2.73 2.53 2.64 2.71 2.38 2.48 2.33 2.14 2.28 2.02 1.77 2.02 2.11 1.74 1.74 1.63 1.84 1.93 1.87 2.11 1.70 1.96 1.96 2.05 1.63 1.47 1.47 1.77 1.47 1.77 1.47 1.25 1.51 1.43 1.66 1.47 1.34 1.25 1.39 1.43 1.25 1.47 0.92 1.34 1.20 1.34 1.34 1.34 1.47 1.20 1.15 1.20 1.10 1.04 0.98 1.25 1.10 0.98 0.98 1.20 1.04 1.20 0.92 1.55 1.20 1.39 1.25 0.98 1.15 1.04 1.47 1.30 1.04 1.43 1.43 1.30 0.92 0.92 1.20 1.20 1.34 0.78 1.30 1.10 1.15 1.20 1.04 1.04 1.34 1.30 0.98 1.10 1.25 1.20 1.15 1.30 1.47 1.04 1.10 1.43 1.20 1.34 1.30 1.25 1.51 1.10 1.55 1.43 1.51 1.04 1.20 1.202007-09-01Comment of the Producer: Ion efficiency curves for the negative ions (M-OH)– formed upon DEA to the three isomers of mono-nitrotoluene. The ion yield for 4-NT is multiplied by 0.15 for better comparison. All anion yields are measured with the monochromator instrument. Additional Comment: X-Values are measured with an energy resolution of 0.080 eV. Therefore every shown peak is the original peak shape convoluted with our resolution. Energy scans are calibrated. Therefore we estimate an error of 0.1 eVBIDEADB-13elatEDAXIDEADB-109XIDEADB-electronXIDEADB-113Energy of the impact electron0.1Ion Yield3.32 1.73 2.45 2.00 2.65 1.73 1.00 1.00 1.73 1.41 2.00 2.00 2.45 1.41 2.00 2.24 3.00 1.41 3.00 2.83 3.00 4.00 4.00 4.80 3.87 3.46 5.29 5.10 3.46 3.87 5.10 5.57 5.66 4.90 6.08 5.57 6.48 5.39 6.08 6.48 6.24 5.92 6.93 6.63 6.56 6.48 5.92 5.92 6.56 5.83 6.16 6.24 6.40 5.74 6.24 4.90 5.92 5.83 6.48 5.10 5.66 5.00 4.69 4.69 4.24 3.87 4.58 4.36 3.74 3.87 4.00 3.16 3.46 3.87 3.32 3.87 4.00 2.83 2.83 2.83 2.00 4.12 3.16 3.16 3.61 2.83 2.00 3.74 4.00 3.32 4.12 3.46 3.32 4.80 4.36 4.80 5.57 5.57 4.90 5.39 5.48 6.93 6.48 7.07 8.60 7.55 8.19 8.77 9.90 10.86 10.10 11.45 12.57 12.96 14.66 14.11 16.25 17.26 17.41 17.97 18.30 19.62 19.90 21.38 21.52 22.16 23.75 25.18 25.55 25.79 27.22 28.37 28.05 29.43 28.97 30.66 31.75 32.20 32.80 32.92 33.97 35.01 34.71 35.75 35.44 36.58 36.00 38.04 36.80 37.31 38.60 38.31 38.92 39.09 38.82 38.48 38.46 39.95 39.48 39.20 38.76 37.97 38.03 37.97 37.52 38.03 37.05 36.33 36.08 36.67 33.82 34.94 33.93 33.93 34.21 32.77 32.71 31.34 31.50 29.97 30.59 29.92 30.05 28.25 27.84 26.42 27.07 25.34 25.51 25.28 24.60 23.52 22.76 21.91 21.95 21.95 20.12 19.80 19.70 17.92 18.47 17.72 17.29 15.72 16.00 15.43 14.25 13.78 13.67 13.00 11.36 11.53 10.10 11.22 10.34 9.95 9.38 9.80 9.17 8.77 9.22 8.00 8.60 7.14 8.31 8.25 6.93 7.35 7.35 6.56 6.56 7.00 6.08 6.32 5.92 6.24 6.71 6.00 5.29 5.48 6.16 4.69 6.24 4.47 5.74 5.10 5.20 5.00 5.66 4.24 5.57 4.69 4.58 4.90 5.10 4.24 4.58 4.00 4.00 4.12 3.87 4.36 4.47 4.47 4.00 3.74 4.24 4.24 3.61 3.74 3.61 4.58 3.87 3.002007-09-01Comment of the Producer: Ion efficiency curves for the negative ions (M-H2O)– formed upon DEA to the three isomers of mono-nitrotoluene. Additional Comment: X-Values are measured with an energy resolution of 1.000 eV. Therefore every shown peak is the original peak shape convoluted with our resolution. Energy scans are calibrated. Therefore we estimate an error of 0.1 eVBIDEADB-13elatEDAXIDEADB-109XIDEADB-electronXIDEADB-114Energy of the impact electron0.1Ion Yield0.44 0.45 0.47 0.46 0.48 0.50 0.51 0.52 0.56 0.59 0.62 0.65 0.71 0.72 0.77 0.82 0.89 0.92 0.94 0.98 1.03 1.02 1.07 1.09 1.10 1.09 1.13 1.11 1.08 1.06 1.04 1.02 0.97 0.95 0.89 0.87 0.87 0.84 0.77 0.71 0.68 0.68 0.64 0.63 0.62 0.64 0.64 0.65 0.67 0.72 0.70 0.79 0.82 0.91 0.97 1.03 1.15 1.19 1.28 1.37 1.48 1.56 1.61 1.72 1.81 1.93 2.02 2.11 2.20 2.32 2.44 2.54 2.61 2.72 2.84 2.92 2.98 3.04 3.10 3.15 3.12 3.16 3.16 3.15 3.15 3.14 3.07 2.99 2.93 2.85 2.77 2.63 2.55 2.46 2.32 2.23 2.10 1.96 1.86 1.75 1.63 1.54 1.46 1.35 1.30 1.14 1.08 1.02 0.96 0.89 0.83 0.80 0.76 0.73 0.72 0.68 0.62 0.64 0.57 0.59 0.57 0.57 0.55 0.56 0.54 0.54 0.56 0.54 0.53 0.52 0.55 0.52 0.53 0.52 0.54 0.53 0.55 0.56 0.55 0.55 0.55 0.57 0.55 0.55 0.54 0.55 0.54 0.56 0.56 0.58 0.58 0.57 0.57 0.56 0.57 0.59 0.58 0.60 0.57 0.58 0.59 0.58 0.62 0.58 0.59 0.60 0.59 0.59 0.60 0.60 0.61 0.63 0.61 0.61 0.60 0.60 0.62 0.63 0.61 0.62 0.60 0.64 0.61 0.60 0.64 0.61 0.63 0.62 0.64 0.63 0.61 0.63 0.63 0.63 0.63 0.64 0.64 0.62 0.63 0.64 0.64 0.63 0.62 0.60 0.62 0.64 0.62 0.64 0.62 0.64 0.62 0.61 0.64 0.64 0.62 0.65 0.63 0.65 0.62 0.64 0.61 0.64 0.61 0.64 0.65 0.59 0.66 0.63 0.63 0.59 0.61 0.64 0.63 0.65 0.63 0.63 0.63 0.64 0.63 0.63 0.61 0.62 0.63 0.61 0.60 0.62 0.60 0.61 0.61 0.61 0.59 0.64 0.62 0.60 0.62 0.59 0.63 0.60 0.62 0.62 0.62 0.61 0.62 0.63 0.61 0.62 0.64 0.58 0.61 0.60 0.63 0.622007-09-01Comment of the Producer: Ion efficiency curves for the negative ions (M-H2O)– formed upon DEA to the three isomers of mono-nitrotoluene. Additional Comment: X-Values are measured with an energy resolution of 0.080 eV. Therefore every shown peak is the original peak shape convoluted with our resolution. Energy scans are calibrated. Therefore we estimate an error of 0.1 eVBIDEADB-13elatEDAXIDEADB-109XIDEADB-electronXIDEADB-114Energy of the impact electron0.1Ion Yield0.20 0.34 0.20 0.28 0.16 0.16 0.16 0.11 0.11 0.00 0.20 0.16 0.11 0.16 0.20 0.25 0.16 0.20 0.23 0.28 0.36 0.20 0.20 0.47 0.41 0.49 0.49 0.55 0.48 0.58 0.58 0.61 0.72 0.85 0.68 0.71 0.72 0.91 0.85 0.82 0.94 0.88 0.93 0.90 0.95 1.03 1.15 1.12 0.91 1.10 1.04 1.07 1.03 1.07 1.14 1.10 1.07 1.05 1.10 1.09 0.90 0.91 0.76 0.83 0.75 0.78 0.72 0.64 0.52 0.63 0.54 0.52 0.53 0.49 0.42 0.45 0.45 0.45 0.30 0.39 0.34 0.28 0.25 0.11 0.32 0.25 0.32 0.25 0.23 0.23 0.36 0.28 0.25 0.30 0.20 0.20 0.25 0.23 0.44 0.38 0.36 0.36 0.34 0.53 0.42 0.42 0.54 0.42 0.49 0.53 0.49 0.60 0.67 0.77 0.69 0.85 0.90 0.93 1.04 1.07 1.12 1.11 1.17 1.34 1.33 1.35 1.45 1.55 1.66 1.76 1.83 1.82 2.05 2.03 2.14 2.13 2.25 2.27 2.33 2.35 2.44 2.59 2.68 2.74 2.74 2.67 2.82 2.79 2.93 2.94 3.00 3.03 3.04 3.04 3.10 3.13 3.05 3.12 3.04 3.16 3.12 3.11 3.10 3.11 2.96 3.06 2.93 2.99 2.90 2.95 2.90 2.83 2.85 2.69 2.62 2.50 2.44 2.35 2.34 2.29 2.27 2.24 2.13 2.06 2.08 2.04 1.90 1.76 1.75 1.74 1.61 1.55 1.52 1.51 1.35 1.44 1.35 1.28 1.24 1.09 1.13 1.11 1.11 1.11 1.05 0.88 0.91 0.95 0.84 0.78 0.84 0.82 0.73 0.65 0.70 0.70 0.64 0.54 0.60 0.65 0.67 0.61 0.63 0.57 0.53 0.52 0.62 0.47 0.45 0.39 0.53 0.52 0.41 0.54 0.45 0.41 0.32 0.47 0.39 0.39 0.39 0.41 0.30 0.34 0.30 0.30 0.34 0.28 0.28 0.36 0.34 0.32 0.38 0.41 0.41 0.41 0.41 0.38 0.28 0.30 0.30 0.23 0.25 0.38 0.25 0.20 0.25 0.42 0.30 0.34 0.34 0.25 0.25 0.25 0.34 0.302007-09-01X-Values are measured with an energy resolution of 0.080 eV. Therefore every shown peak is the original peak shape convoluted with our resolution. Energy scans are calibrated. Therefore we estimate an error of 0.1 eVBIDEADB-13elatEDAXIDEADB-109XIDEADB-electronXIDEADB-115Energy of the impact electron0.1Ion Yield8.37 8.17 7.54 7.01 6.66 5.55 4.52 4.10 3.58 3.63 2.90 3.35 4.29 4.00 4.20 4.15 5.33 5.02 6.48 6.48 7.38 7.59 8.65 8.44 8.27 9.59 10.08 11.40 10.99 10.75 12.63 12.47 12.99 13.43 13.81 14.74 14.98 15.43 15.76 16.09 16.14 16.33 16.97 17.65 17.49 17.48 18.61 18.30 18.69 18.88 18.76 19.39 19.81 19.13 19.67 20.10 19.67 19.93 20.01 19.78 19.93 19.31 19.60 19.29 18.28 18.43 18.08 17.80 17.31 16.61 15.91 15.86 15.23 15.23 14.51 13.25 13.89 12.98 12.28 11.51 10.66 10.37 10.47 10.00 9.36 9.21 8.32 8.51 8.32 7.64 7.77 7.18 6.39 6.66 6.42 5.90 5.83 6.16 5.40 5.51 6.00 5.83 5.06 5.76 5.76 5.18 5.59 5.62 5.66 6.13 5.22 6.32 6.66 6.75 6.84 6.29 6.54 7.10 7.35 7.56 8.41 8.39 8.39 8.32 9.38 9.40 9.86 9.63 10.58 11.47 11.28 12.39 12.41 13.24 13.43 13.97 14.82 14.75 15.38 15.81 16.69 16.64 17.37 18.87 18.74 19.10 19.77 20.37 20.90 21.04 21.71 21.96 22.49 24.12 23.97 24.40 24.12 25.15 25.32 25.91 26.28 26.71 27.78 27.35 27.20 28.26 28.53 29.15 29.07 29.10 29.79 30.15 29.89 29.78 30.40 30.29 30.95 30.49 30.97 30.56 32.24 31.42 31.00 31.46 31.09 31.06 31.08 30.74 30.98 31.34 30.68 31.00 30.47 30.65 30.11 30.34 30.13 29.48 29.46 29.14 29.24 29.11 28.72 28.63 28.21 27.68 26.91 26.76 26.57 26.18 25.86 25.24 24.48 24.14 23.94 23.62 23.58 23.27 22.49 21.48 21.66 20.99 20.47 20.40 20.22 19.78 19.44 19.09 17.65 17.94 17.79 17.62 16.12 15.92 16.38 15.39 15.11 15.43 14.38 13.89 13.87 13.77 13.02 12.71 12.03 12.07 11.26 11.58 11.05 10.66 10.43 11.03 10.26 10.10 10.20 9.42 8.99 9.42 9.19 8.67 8.83 8.97 8.83 7.54 7.27 8.07 7.10 7.51 7.29 6.63 6.32 6.00 5.57 5.74 5.20 5.83 4.58 4.60 4.60 4.60 4.60 4.60 4.60 4.60 4.60 4.60 4.60 4.60 4.60 4.60 4.86 5.10 5.18 5.31 5.44 5.53 5.43 5.17 5.28 5.17 5.06 4.94 4.68 4.86 5.19 5.28 5.32 5.13 5.10 5.42 5.41 5.78 5.80 5.53 5.32 5.65 5.47 5.52 5.44 5.22 5.23 5.55 6.33 6.46 6.44 6.56 6.51 6.73 6.94 7.03 6.46 6.58 7.11 6.58 7.06 7.46 7.85 7.89 8.17 8.65 8.86 9.49 9.49 9.67 9.89 10.03 10.04 10.02 9.95 9.86 9.82 9.70 9.67 9.57 9.44 9.37 9.21 9.17 9.24 9.14 9.01 8.70 8.45 8.40 7.88 7.84 7.37 6.99 6.47 7.01 7.18 6.91 7.39 7.27 7.23 7.06 7.23 7.43 7.33 6.87 6.74 6.93 6.91 7.00 7.01 7.14 7.26 7.11 7.38 7.23 7.04 7.24 7.43 7.09 6.52 6.63 6.50 6.82 7.24 6.86 7.05 7.23 7.12 7.34 7.45 7.66 7.98 8.20 8.31 8.26 8.20 8.38 8.38 8.38 8.38 8.38 8.38 8.38 8.38 8.38 8.38 8.38 8.38 8.38 8.38 8.38 8.38 8.38 1.41 1.41 1.412007-09-01X-Values are measured with an energy resolution of 0.080 eV. Therefore every shown peak is the original peak shape convoluted with our resolution. Energy scans are calibrated. Therefore we estimate an error of 0.1 eVBIDEADB-13elatEDAXIDEADB-109XIDEADB-electronXIDEADB-116Energy of the impact electron0.1Ion Yield0.59 0.42 0.00 0.54 0.34 0.34 0.34 0.34 0.24 0.34 0.24 0.34 0.42 0.34 0.42 0.48 0.42 0.24 0.68 0.54 0.48 0.24 0.54 0.42 0.59 0.48 0.54 0.59 0.63 0.76 0.80 0.86 0.63 0.90 0.76 0.99 0.72 0.72 0.54 0.59 0.63 0.72 0.96 0.83 0.86 0.83 0.80 0.76 0.68 0.63 0.54 0.48 0.48 0.54 0.48 0.24 0.54 0.68 0.59 0.34 0.00 0.48 0.34 0.59 0.48 0.00 0.34 0.72 0.42 0.54 0.76 0.63 0.54 0.54 0.48 0.34 0.59 0.48 0.63 0.83 0.80 0.54 0.86 0.93 0.63 0.96 0.90 1.07 1.12 1.12 0.99 1.10 1.10 1.52 1.38 1.48 1.93 1.81 1.86 2.30 2.29 2.47 2.88 3.17 3.13 3.49 3.77 4.28 4.36 4.62 5.31 5.56 6.08 6.48 7.07 7.60 8.14 8.69 9.18 9.85 10.12 10.94 11.49 12.15 12.45 13.37 14.00 14.39 14.85 15.51 16.04 16.44 16.64 16.93 17.28 17.63 17.64 17.82 18.30 18.15 18.16 18.29 18.27 18.21 18.27 17.98 17.70 17.68 17.37 17.32 16.89 16.75 16.17 16.00 15.73 15.55 14.93 14.83 14.37 14.08 13.81 13.39 13.20 12.76 12.26 12.02 11.56 11.25 10.84 10.68 10.14 10.09 9.70 9.10 9.16 8.93 8.46 8.38 8.16 7.61 7.47 7.01 6.98 6.52 6.42 5.91 6.01 5.56 5.32 5.39 5.23 5.06 4.85 4.76 4.49 4.46 4.10 4.10 4.03 3.93 3.63 3.69 3.67 3.64 3.51 3.52 3.14 3.19 3.15 2.91 2.97 2.94 3.01 3.01 2.97 2.88 2.76 3.07 3.11 2.78 3.05 2.94 2.97 3.25 3.12 3.13 3.23 3.36 3.57 3.58 3.54 3.43 3.74 3.54 3.84 3.98 4.06 3.96 4.21 4.07 4.10 4.28 4.15 4.15 4.35 4.32 4.48 4.46 4.61 4.30 4.49 4.49 4.51 4.27 4.33 4.67 4.23 4.40 4.47 4.42 4.12 4.15 4.23 4.12 4.27 4.24 4.00 3.87 4.05 3.85 3.84 3.74 3.64 3.63 3.54 3.22 3.48 3.36 3.31 3.33 3.172007-09-01Comment of the Producer: The abundance of (M-NO2)– is about five times higher for 2-NT compared to the other isomers and for better comparison multiplied with a factor of 0.25. Additional Comment: X-Values are measured with an energy resolution of 0.080 eV. Therefore every shown peak is the original peak shape convoluted with our resolution. Energy scans are calibrated. Therefore we estimate an error of 0.1 eVBIDEADB-13elatEDAXIDEADB-109XIDEADB-electronXIDEADB-117Energy of the impact electron0.1Ion Yield1.94 2.24 1.94 1.12 1.58 1.12 1.12 1.12 0.00 1.12 0.00 1.12 0.00 0.00 1.12 1.12 1.58 1.12 0.00 1.12 0.00 1.58 1.12 2.50 1.12 1.94 1.94 2.24 2.74 2.74 2.74 2.50 2.24 3.35 3.71 3.87 3.35 4.03 2.24 3.35 4.33 3.71 2.74 3.16 3.71 3.16 2.74 2.96 2.50 1.12 2.74 2.24 1.12 2.74 1.94 1.58 1.12 2.24 1.94 1.12 1.58 1.58 1.12 1.58 0.00 1.12 1.12 1.94 1.94 1.12 1.94 1.12 1.12 1.58 1.12 1.12 0.00 1.58 2.24 1.58 2.96 1.12 1.58 2.74 1.12 3.71 2.74 3.54 4.33 2.96 4.87 3.87 3.54 5.36 6.22 5.36 6.98 6.32 6.52 6.89 8.06 7.75 8.80 8.37 7.83 9.62 8.22 9.29 11.51 11.73 11.51 12.70 13.65 13.28 13.37 13.83 14.75 14.62 14.71 16.20 14.79 16.20 17.39 16.43 16.58 16.20 17.89 17.46 17.99 18.13 18.27 17.75 17.75 17.46 18.77 17.89 18.64 17.50 17.54 16.16 16.96 15.41 15.65 14.71 15.81 15.33 14.75 14.53 13.74 13.37 13.18 12.60 12.30 12.35 11.88 10.90 10.78 11.46 10.19 10.25 10.25 10.31 10.55 10.37 10.55 10.67 10.90 11.83 10.61 11.12 11.01 12.35 12.14 12.09 11.24 12.75 11.94 12.99 12.04 13.83 13.09 14.19 15.61 15.21 14.87 14.40 16.36 15.89 15.69 16.88 16.81 16.28 16.32 17.14 17.10 17.54 18.06 16.99 15.49 17.28 16.84 17.03 15.33 15.85 16.43 16.43 15.85 14.53 16.09 14.58 14.71 14.27 13.37 13.92 14.23 13.04 13.37 11.62 11.24 11.46 9.87 10.90 10.00 10.55 9.01 9.15 9.94 8.29 8.59 8.29 7.75 6.42 7.83 7.25 6.32 7.25 6.98 7.58 5.24 6.71 6.61 5.36 6.12 6.42 6.71 6.89 7.83 7.75 6.71 6.71 5.70 6.42 7.25 7.25 7.33 6.89 6.22 7.83 6.52 7.75 7.33 8.14 7.25 6.42 6.12 7.33 6.02 6.71 6.80 7.582007-09-01Comment of the Producer: The ion efficiency curves for 2-NT are multiplied with 0.2 for better comparison with the other isomers. Additional Comment: X-Values are measured with an energy resolution of 1.000 eV. Therefore every shown peak is the original peak shape convoluted with our resolution. Energy scans are calibrated. Therefore we estimate an error of 0.1 eVBIDEADB-13elatEDAXIDEADB-109XIDEADB-electronXIDEADB-119Energy of the impact electron0.1Ion Yield0.17 0.17 0.22 0.24 0.28 0.27 0.30 0.32 0.37 0.35 0.42 0.42 0.45 0.50 0.52 0.55 0.59 0.59 0.65 0.66 0.67 0.67 0.69 0.72 0.74 0.77 0.79 0.79 0.76 0.79 0.80 0.84 0.82 0.86 0.88 0.90 0.96 0.96 1.03 1.05 1.12 1.18 1.23 1.31 1.39 1.44 1.57 1.66 1.74 1.86 1.95 2.07 2.13 2.28 2.37 2.46 2.52 2.63 2.74 2.83 2.90 3.00 3.04 3.14 3.21 3.29 3.32 3.37 3.39 3.42 3.38 3.43 3.36 3.30 3.28 3.26 3.19 3.15 3.07 3.00 2.89 2.84 2.73 2.64 2.58 2.45 2.34 2.26 2.18 2.08 2.00 1.91 1.81 1.78 1.69 1.60 1.52 1.48 1.38 1.34 1.28 1.23 1.16 1.11 1.05 1.04 1.00 0.96 0.94 0.86 0.86 0.85 0.83 0.79 0.77 0.75 0.75 0.73 0.74 0.72 0.72 0.69 0.74 0.71 0.69 0.71 0.71 0.69 0.73 0.71 0.70 0.71 0.70 0.71 0.70 0.77 0.73 0.74 0.75 0.73 0.70 0.73 0.71 0.72 0.75 0.72 0.76 0.74 0.74 0.71 0.75 0.72 0.70 0.76 0.73 0.71 0.73 0.73 0.75 0.77 0.73 0.72 0.72 0.76 0.75 0.73 0.76 0.78 0.76 0.73 0.77 0.73 0.76 0.79 0.79 0.76 0.79 0.82 0.80 0.76 0.82 0.79 0.79 0.77 0.80 0.81 0.81 0.81 0.80 0.77 0.79 0.82 0.80 0.78 0.78 0.78 0.79 0.80 0.80 0.78 0.79 0.82 0.79 0.77 0.78 0.78 0.75 0.77 0.75 0.76 0.76 0.76 0.76 0.76 0.76 0.74 0.78 0.73 0.74 0.74 0.74 0.76 0.74 0.74 0.73 0.71 0.75 0.73 0.72 0.72 0.76 0.74 0.74 0.73 0.76 0.74 0.74 0.69 0.75 0.70 0.72 0.71 0.73 0.75 0.71 0.73 0.72 0.74 0.72 0.702007-09-01Comment of the Producer: The ion efficiency curves for 2-NT are multiplied with 0.2 for better comparison with the other isomers. Additional Comment: X-Values are measured with an energy resolution of 0.080 eV. Therefore every shown peak is the original peak shape convoluted with our resolution. Energy scans are calibrated. Therefore we estimate an error of 0.1 eVBIDEADB-13elatEDAXIDEADB-109XIDEADB-electronXIDEADB-119Energy of the impact electron0.1Ion Yield0.26 0.16 0.07 0.17 0.00 0.12 0.00 0.10 0.00 0.07 0.00 0.10 0.07 0.07 0.10 0.16 0.07 0.07 0.00 0.00 0.07 0.14 0.12 0.10 0.07 0.00 0.00 0.14 0.14 0.14 0.07 0.16 0.10 0.20 0.17 0.12 0.14 0.12 0.16 0.17 0.34 0.19 0.28 0.17 0.26 0.26 0.35 0.29 0.36 0.39 0.31 0.42 0.46 0.50 0.43 0.51 0.55 0.49 0.51 0.57 0.51 0.60 0.55 0.62 0.57 0.62 0.60 0.61 0.61 0.53 0.61 0.52 0.50 0.48 0.48 0.54 0.52 0.50 0.50 0.48 0.38 0.47 0.43 0.42 0.44 0.41 0.44 0.48 0.44 0.44 0.53 0.47 0.57 0.59 0.58 0.59 0.68 0.72 0.71 0.74 0.85 0.88 0.91 1.01 1.07 1.02 1.14 1.23 1.27 1.31 1.45 1.44 1.58 1.68 1.73 1.93 1.94 2.02 2.05 2.23 2.20 2.37 2.46 2.56 2.59 2.67 2.77 2.78 2.88 3.02 3.00 3.08 3.08 3.14 3.20 3.18 3.17 3.23 3.25 3.32 3.41 3.34 3.37 3.35 3.43 3.37 3.42 3.37 3.33 3.42 3.32 3.34 3.39 3.34 3.30 3.27 3.27 3.24 3.12 3.10 3.15 3.07 3.09 2.95 2.95 2.93 2.90 2.88 2.71 2.67 2.68 2.68 2.61 2.55 2.48 2.45 2.41 2.40 2.41 2.25 2.18 2.17 2.19 2.08 2.01 1.96 1.97 1.89 1.90 1.73 1.82 1.81 1.70 1.66 1.65 1.64 1.60 1.59 1.50 1.49 1.46 1.41 1.33 1.41 1.22 1.26 1.31 1.20 1.26 1.15 1.18 1.09 1.05 1.08 0.99 0.99 0.99 1.03 0.92 0.95 0.89 0.82 0.85 0.87 0.78 0.75 0.78 0.81 0.77 0.76 0.72 0.74 0.67 0.73 0.65 0.64 0.66 0.65 0.53 0.60 0.60 0.49 0.57 0.55 0.63 0.57 0.49 0.55 0.54 0.53 0.53 0.55 0.53 0.48 0.46 0.48 0.48 0.46 0.50 0.47 0.46 0.46 0.48 0.52 0.44 0.50 0.46 0.47 0.43 0.42 0.42 0.46 0.48 0.38 0.43 0.392007-09-01Comment of the Producer: Ion efficiency curves for the parent negative ions of the three mono-nitrotoluene isomers (m/z=137). Additional Comment: X-Values are measured with an energy resolution of 0.080 eV. Therefore every shown peak is the original peak shape convoluted with our resolution. Energy scans are calibrated. Therefore we estimate an error of 0.1 eVBIDEADB-13elatEDAXIDEADB-110XIDEADB-electronXIDEADB-110Energy of the impact electron0.1Ion Yield330.45 330.41 326.46 319.55 312.95 304.58 294.53 284.90 274.97 265.94 255.18 244.64 233.38 224.56 212.17 201.14 192.18 184.28 174.69 168.29 161.64 157.52 152.10 146.71 142.93 138.37 133.17 126.62 121.53 116.63 110.86 102.32 95.87 87.89 80.44 74.02 66.45 60.23 54.45 49.70 43.41 40.52 36.84 33.91 31.13 29.34 27.04 24.64 23.17 22.00 21.14 19.90 18.97 18.06 16.94 17.86 16.97 16.06 16.82 16.092007-09-01Comment of the Producer: Ion efficiency curves for the closed shell negative ions (M-H)– formed via loss of a neutral hydrogen atom for the three isomers of mono-nitrotoluene. All anion yields are measured with the monochromator instrument. Additional Comment: X-Values are measured with an energy resolution of 0.080 eV. Therefore every shown peak is the original peak shape convoluted with our resolution. Energy scans are calibrated. Therefore we estimate an error of 0.1 eVBIDEADB-13elatEDAXIDEADB-110XIDEADB-electronXIDEADB-112Energy of the impact electron0.1Ion Yield0.29 0.11 0.22 0.32 0.38 0.43 0.39 0.45 0.43 0.50 0.55 0.58 0.59 0.58 0.56 0.53 0.47 0.29 0.36 0.45 0.45 0.43 0.40 0.34 0.25 0.31 0.24 0.34 0.33 0.31 0.29 0.25 0.20 0.10 0.15 0.25 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.25 0.15 0.10 0.20 0.25 0.29 0.31 0.33 0.34 0.24 0.18 0.31 0.39 0.36 0.43 0.34 0.39 0.18 0.24 0.50 0.77 0.71 0.92 1.16 1.23 1.41 1.52 1.58 1.75 2.05 2.38 2.63 3.03 3.37 3.61 3.93 4.29 4.69 5.09 5.42 5.71 5.99 6.31 6.67 6.98 7.23 7.52 7.85 8.21 8.50 8.81 9.16 9.40 9.75 9.94 10.28 10.56 10.66 10.75 10.92 11.14 11.28 11.45 11.49 11.48 11.46 11.50 11.44 11.39 11.29 11.00 10.79 10.50 10.28 9.90 9.41 8.98 8.62 8.22 7.76 7.35 6.74 6.21 5.80 5.50 5.14 4.81 4.38 3.97 3.81 3.66 3.43 3.24 2.94 2.70 2.63 2.45 2.27 2.12 1.95 1.95 1.83 1.83 1.86 1.90 1.81 1.71 1.68 1.66 1.60 1.52 1.48 1.49 1.43 1.40 1.22 1.14 1.13 1.12 1.11 1.09 1.17 1.21 1.15 1.10 1.24 1.21 1.19 1.25 1.26 1.23 1.08 1.11 1.14 1.29 1.24 1.33 1.35 1.50 1.62 1.75 1.77 1.95 2.10 2.18 2.44 2.65 2.75 2.93 3.13 3.32 3.37 3.50 3.69 3.87 3.95 4.21 4.36 4.56 4.66 4.81 4.88 4.95 5.11 5.09 5.04 5.03 4.96 4.82 4.71 4.73 4.63 4.56 4.38 4.41 4.28 4.27 4.16 4.10 4.02 3.95 3.88 3.60 3.45 3.50 3.45 3.39 3.29 3.26 3.25 3.19 3.03 3.16 2.99 3.06 2.82 2.86 2.81 2.76 2.67 2.55 2.55 2.36 2.32 2.28 2.18 2.20 2.17 2.14 2.06 2.12 2.02 2.00 1.97 1.96 1.92 1.88 1.77 1.73 1.79 1.60 1.77 1.72 1.72 1.78 1.80 1.83 1.91 1.90 1.90 1.90 1.90 1.90 1.90 1.90 1.90 1.90 1.902007-09-01Comment of the Producer: Ion efficiency curves for the negative ions (M-OH)– formed upon DEA to the three isomers of mono-nitrotoluene. The ion yield for 4-NT is multiplied by 0.15 for better comparison. All anion yields are measured with the monochromator instrument. Additional Comment: X-Values are measured with an energy resolution of 0.080 eV. Therefore every shown peak is the original peak shape convoluted with our resolution. Energy scans are calibrated. Therefore we estimate an error of 0.1 eVBIDEADB-13elatEDAXIDEADB-110XIDEADB-electronXIDEADB-113Energy of the impact electron0.1Ion Yield0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 2.05 0.00 0.00 0.00 2.51 1.45 2.05 0.00 2.90 4.10 3.55 2.90 2.51 2.90 4.81 5.02 5.02 5.22 6.48 6.48 7.25 8.69 8.57 8.69 10.35 12.21 9.39 11.86 12.47 12.12 12.80 13.59 15.40 14.92 14.85 15.27 14.71 16.90 18.10 17.92 18.89 19.92 20.13 20.34 19.50 22.68 22.26 22.91 23.50 22.64 24.03 25.72 25.84 26.60 26.84 27.76 28.17 30.12 29.73 32.01 31.38 32.27 34.20 32.66 34.42 34.87 34.81 34.90 35.59 36.26 37.51 37.73 38.26 37.14 37.76 38.53 38.86 38.29 37.84 39.26 38.69 39.71 39.13 39.47 40.42 38.97 38.40 38.91 38.78 37.31 37.57 36.66 35.02 37.37 35.17 35.32 32.60 33.80 33.20 32.85 30.77 30.05 30.29 30.43 29.80 28.40 26.88 27.95 26.56 26.12 25.31 23.77 23.86 22.21 23.05 20.85 20.60 18.73 20.08 20.29 19.39 18.33 17.45 17.92 17.27 17.69 15.34 15.40 14.42 13.44 12.80 14.12 12.04 12.12 11.95 11.77 10.14 9.17 10.84 9.28 9.83 8.45 8.32 7.67 6.95 6.15 7.94 7.39 7.10 6.32 7.80 6.80 6.15 5.22 7.25 6.15 6.80 5.97 6.80 5.42 5.02 5.80 5.22 5.22 5.42 3.83 4.58 4.81 5.02 5.22 4.35 4.81 2.90 3.83 3.55 3.55 2.90 4.58 2.90 2.05 3.24 3.83 0.00 3.24 3.83 2.90 3.552007-09-01Comment of the Producer: Ion efficiency curves for the negative ions (M-H2O)– formed upon DEA to the three isomers of mono-nitrotoluene. Additional Comment: X-Values are measured with an energy resolution of 1.000 eV. Therefore every shown peak is the original peak shape convoluted with our resolution. Energy scans are calibrated. Therefore we estimate an error of 0.1 eVBIDEADB-13elatEDAXIDEADB-110XIDEADB-electronXIDEADB-114Energy of the impact electron0.1Ion Yield0.06 0.07 0.08 0.08 0.06 0.08 0.09 0.08 0.09 0.11 0.09 0.09 0.11 0.10 0.11 0.11 0.13 0.12 0.14 0.14 0.13 0.16 0.15 0.20 0.19 0.21 0.22 0.24 0.24 0.24 0.25 0.28 0.28 0.28 0.28 0.31 0.32 0.36 0.40 0.43 0.48 0.52 0.54 0.62 0.66 0.72 0.79 0.86 0.94 1.02 1.08 1.16 1.28 1.38 1.50 1.57 1.69 1.82 1.92 2.02 2.11 2.22 2.35 2.42 2.53 2.60 2.70 2.79 2.88 2.94 2.98 3.03 3.08 3.13 3.13 3.16 3.16 3.15 3.16 3.13 3.09 3.04 2.99 2.93 2.89 2.81 2.73 2.61 2.56 2.47 2.38 2.29 2.19 2.10 1.99 1.90 1.81 1.71 1.62 1.54 1.47 1.39 1.33 1.25 1.18 1.14 1.06 1.03 0.97 0.95 0.89 0.85 0.81 0.77 0.75 0.73 0.70 0.69 0.68 0.65 0.63 0.61 0.61 0.61 0.61 0.61 0.58 0.56 0.59 0.60 0.56 0.57 0.58 0.57 0.58 0.58 0.58 0.59 0.60 0.59 0.58 0.60 0.60 0.62 0.61 0.61 0.62 0.59 0.59 0.63 0.61 0.61 0.59 0.59 0.61 0.61 0.61 0.61 0.63 0.62 0.61 0.63 0.61 0.63 0.62 0.64 0.63 0.63 0.64 0.63 0.64 0.63 0.66 0.65 0.66 0.67 0.66 0.68 0.65 0.69 0.66 0.66 0.68 0.67 0.67 0.67 0.67 0.67 0.67 0.67 0.67 0.69 0.66 0.67 0.69 0.68 0.68 0.67 0.69 0.71 0.69 0.69 0.68 0.69 0.71 0.68 0.69 0.69 0.69 0.68 0.70 0.69 0.72 0.67 0.69 0.67 0.69 0.68 0.69 0.67 0.70 0.70 0.70 0.68 0.70 0.67 0.69 0.68 0.68 0.68 0.70 0.66 0.68 0.69 0.67 0.67 0.67 0.69 0.67 0.68 0.68 0.67 0.68 0.69 0.70 0.66 0.67 0.68 0.69 0.68 0.69 0.70 0.69 0.69 0.67 0.70 0.70 0.69 0.68 0.68 0.67 0.68 0.69 0.68 0.68 0.68 0.68 0.70 0.70 0.69 0.69 0.70 0.69 0.67 0.70 0.68 0.68 0.68 0.68 0.71 0.69 0.67 0.69 0.71 0.68 0.69 0.70 0.69 0.69 0.66 0.69 0.69 0.67 0.69 0.72 0.68 0.712007-09-01X-Values are measured with an energy resolution of 0.080 eV. Therefore every shown peak is the original peak shape convoluted with our resolution. Energy scans are calibrated. Therefore we estimate an error of 0.1 eVBIDEADB-13elatEDAXIDEADB-110XIDEADB-electronXIDEADB-115Energy of the impact electron0.1Ion Yield0.00 0.00 1.00 0.00 0.00 0.00 0.00 0.00 1.00 0.00 0.00 0.00 1.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 1.00 0.00 0.00 0.00 0.00 1.00 0.00 0.00 1.00 1.41 0.00 0.00 1.00 0.00 1.00 1.00 1.73 2.00 1.41 1.00 1.41 2.00 0.00 1.73 2.00 1.41 2.45 1.41 1.00 1.41 2.00 1.41 1.73 0.00 1.73 0.00 1.00 1.73 1.00 1.41 0.00 1.73 2.45 1.00 1.41 1.41 1.00 1.41 2.45 1.73 3.00 3.00 4.36 4.90 4.80 4.69 5.74 6.86 7.94 9.22 10.05 10.30 12.57 12.88 14.97 15.49 16.40 16.82 19.26 19.80 20.15 21.24 22.27 22.49 24.15 25.44 25.02 25.53 26.15 27.64 27.28 27.46 28.90 29.75 28.53 29.09 29.97 29.90 30.79 29.87 31.54 30.66 31.22 31.59 30.28 29.93 30.77 30.64 30.15 29.07 29.80 28.95 28.67 27.33 26.02 26.25 24.64 24.37 23.83 22.74 21.61 22.52 20.37 20.02 19.18 18.17 17.66 17.32 17.23 16.37 16.25 14.25 14.39 13.53 14.07 13.71 12.37 12.17 12.17 11.45 10.77 11.05 11.05 9.00 9.00 8.43 9.11 8.77 9.22 8.06 8.00 8.37 7.75 8.31 7.87 7.55 7.68 7.62 7.42 7.07 7.35 6.86 6.56 6.40 6.48 6.24 6.24 5.10 6.24 5.39 6.16 6.56 6.71 5.74 6.78 5.29 5.48 5.39 5.66 6.32 5.57 6.08 6.00 5.39 6.40 4.80 4.69 5.20 5.20 5.10 4.90 4.80 5.66 4.80 5.48 4.69 5.74 5.39 5.00 6.00 6.16 4.69 4.58 5.20 5.66 5.57 5.00 6.00 5.66 5.00 5.66 5.66 5.29 4.58 5.57 5.57 5.20 5.92 5.48 4.36 5.74 6.00 5.48 5.66 5.74 5.00 5.00 5.66 5.10 6.32 6.56 5.57 5.39 5.57 5.57 6.08 5.66 5.92 6.08 4.58 6.16 5.66 5.48 5.57 5.74 6.08 5.92 5.74 6.16 6.16 6.00 6.56 5.10 5.48 6.63 6.00 6.56 5.83 6.00 5.83 6.08 5.29 5.74 5.57 5.922007-09-01X-Values are measured with an energy resolution of 0.080 eV. Therefore every shown peak is the original peak shape convoluted with our resolution. Energy scans are calibrated. Therefore we estimate an error of 0.1 eVBIDEADB-13elatEDAXIDEADB-110XIDEADB-electronXIDEADB-116Energy of the impact electron0.1Ion Yield0.00 0.46 0.00 0.33 0.00 0.00 0.33 0.00 0.00 0.00 0.00 0.33 0.46 0.33 0.33 0.00 0.33 0.00 0.46 0.46 0.00 0.00 0.57 0.33 0.00 0.00 0.46 0.33 0.00 0.00 0.00 0.00 0.00 0.33 0.00 0.00 0.00 0.33 0.00 0.33 0.00 0.46 0.33 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.33 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.33 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.33 0.00 0.00 0.33 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.33 0.33 0.00 0.33 0.00 0.00 0.00 0.00 0.33 0.33 0.00 0.00 0.00 0.00 0.00 0.33 0.00 0.66 0.57 0.57 0.81 0.57 0.46 0.93 0.99 0.93 0.99 0.99 1.27 1.68 1.14 1.36 1.36 1.61 1.83 2.03 2.08 2.44 2.48 2.83 2.57 2.90 3.22 3.29 3.73 3.81 4.12 4.60 5.06 5.23 5.73 5.96 6.13 6.49 7.48 7.37 8.49 9.22 9.49 9.89 10.71 11.23 11.85 11.98 12.62 13.02 13.87 14.52 14.74 15.36 15.80 16.04 16.47 16.84 17.19 17.85 17.87 18.18 18.38 18.40 18.31 18.53 18.68 18.74 18.92 18.99 18.97 18.59 18.37 18.24 18.20 17.97 17.86 17.71 17.44 17.46 17.05 16.67 16.66 16.20 15.83 15.61 15.60 15.10 14.64 14.35 14.23 14.08 13.84 13.21 12.93 12.84 12.31 11.75 11.68 11.16 11.05 10.52 10.53 10.26 9.89 9.41 9.28 8.82 8.93 8.67 8.18 8.21 7.73 7.27 7.35 7.01 6.72 6.65 6.43 6.37 5.98 5.83 5.79 5.85 5.74 5.49 5.38 5.19 4.83 4.94 4.70 4.88 5.10 4.52 4.26 3.93 4.35 4.09 4.25 3.83 3.89 4.09 3.71 3.68 3.75 3.62 3.40 3.79 3.35 3.59 3.63 3.40 3.40 3.07 3.24 3.15 3.17 3.42 3.08 3.53 3.12 2.98 2.89 3.29 3.34 3.37 2.92 3.08 3.17 3.39 3.17 3.43 3.43 3.60 3.42 3.57 3.45 3.45 3.50 3.53 3.54 3.59 4.01 3.93 4.04 3.73 3.78 4.01 3.66 3.50 3.40 3.63 3.79 3.66 3.92 3.62 3.75 3.34 3.78 3.73 3.60 3.56 3.53 3.60 3.46 3.27 3.42 3.53 3.29 3.27 3.35 3.29 3.25 3.19 2.79 3.00 3.08 3.30 2.92 3.01 2.79 3.15 3.27 2.92 2.92 2.75 3.07 3.05 2.96 3.12 3.10 2.89 2.98 3.03 2.89 2.75 2.98 2.96 3.19 3.14 3.15 3.08 3.15 3.05 3.24 3.14 2.73 2.94 3.08 3.37 3.12 2.77 2.96 2.94 2.75 2.83 3.08 2.77 2.852007-09-01Comment of the Producer: The abundance of (M-NO2)– is about five times higher for 2-NT compared to the other isomers and for better comparison multiplied with a factor of 0.25. Additional Comment: X-Values are measured with an energy resolution of 0.080 eV. Therefore every shown peak is the original peak shape convoluted with our resolution. Energy scans are calibrated. Therefore we estimate an error of 0.1 eVBIDEADB-13elatEDAXIDEADB-110XIDEADB-electronXIDEADB-117Energy of the impact electron0.1Ion Yield0.00 0.00 0.00 0.00 0.00 0.88 1.24 0.00 0.00 0.00 1.24 0.88 1.24 0.88 0.00 0.88 0.00 0.00 0.88 0.00 0.00 0.00 0.00 0.88 0.88 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 1.24 0.00 0.88 0.88 0.00 0.00 0.88 0.00 0.88 1.24 0.88 0.88 0.00 0.00 1.24 0.00 0.88 0.88 0.88 0.88 0.88 0.00 0.00 0.00 0.00 0.00 0.88 1.24 1.52 0.00 1.24 0.88 0.88 1.52 1.75 1.75 1.96 3.04 3.04 3.04 3.62 4.80 4.39 4.11 4.39 5.82 5.82 6.32 6.20 7.13 6.96 6.85 7.02 7.34 9.07 9.11 9.28 9.24 9.92 11.02 11.09 10.71 11.64 11.96 12.06 11.99 12.37 13.56 12.18 12.77 13.36 12.98 12.53 13.36 13.62 12.71 12.40 13.04 11.90 12.12 11.50 11.70 11.64 11.57 11.02 10.56 10.19 10.04 9.24 8.90 9.49 9.16 8.23 8.09 7.89 8.13 7.60 7.39 7.80 7.34 6.96 7.23 7.18 6.32 6.68 6.50 6.91 7.65 6.96 7.39 7.39 7.70 8.04 8.04 9.36 8.86 8.81 9.32 10.85 10.71 10.38 11.96 12.80 12.74 14.38 14.06 14.28 14.33 16.10 15.17 14.88 15.34 16.53 15.69 15.93 14.91 15.57 15.04 14.14 14.57 14.11 13.98 13.53 12.80 11.99 11.83 11.57 11.57 10.08 10.04 9.45 8.77 8.68 8.18 7.99 7.34 6.50 6.79 6.56 6.01 6.56 5.68 6.39 5.48 5.62 6.50 5.41 6.01 4.80 4.88 4.80 4.11 4.39 4.96 5.26 5.33 5.11 4.88 4.64 4.88 5.68 4.80 5.11 4.39 5.41 5.95 4.30 5.88 5.19 5.19 4.39 5.48 4.64 4.56 4.88 3.72 4.02 4.30 4.11 4.21 4.11 4.11 3.04 4.47 4.02 3.92 4.02 3.82 3.72 4.02 3.40 3.04 3.62 2.91 2.63 3.04 3.40 3.51 0.88 3.16 2.32 3.82 2.15 2.48 2.91 3.16 2.91 2.63 2.48 2.63 2.15 1.75 2.32 1.96 1.75 2.48 2.15 3.28 2.48 1.75 1.96 1.24 2.48 2.152007-09-01X-Values are measured with an energy resolution of 0.080 eV. Therefore every shown peak is the original peak shape convoluted with our resolution. Energy scans are calibrated. Therefore we estimate an error of 0.1 eVBIDEADB-13elatEDAXIDEADB-110XIDEADB-electronXIDEADB-119Energy of the impact electron0.1Ion Yield0.08 0.09 0.06 0.13 0.09 0.11 0.07 0.11 0.12 0.14 0.11 0.16 0.13 0.10 0.16 0.17 0.18 0.19 0.21 0.21 0.23 0.23 0.25 0.26 0.31 0.33 0.31 0.36 0.41 0.45 0.43 0.48 0.52 0.51 0.56 0.64 0.64 0.66 0.72 0.75 0.77 0.84 0.85 0.89 0.96 1.04 1.06 1.18 1.24 1.36 1.43 1.47 1.57 1.72 1.77 1.88 1.94 2.06 2.14 2.23 2.36 2.42 2.45 2.59 2.66 2.78 2.83 2.90 2.96 3.00 3.04 3.13 3.06 3.16 3.12 3.12 3.12 3.10 3.10 3.06 3.03 2.98 2.89 2.84 2.78 2.75 2.63 2.55 2.51 2.40 2.34 2.28 2.17 2.09 2.02 1.95 1.90 1.78 1.72 1.68 1.59 1.54 1.51 1.42 1.39 1.38 1.34 1.29 1.29 1.27 1.23 1.24 1.23 1.22 1.22 1.21 1.16 1.13 1.13 1.14 1.12 1.14 1.10 1.07 1.09 1.11 0.99 1.04 1.05 1.00 1.00 0.98 0.98 0.94 0.94 0.92 0.91 0.97 0.89 0.88 0.91 0.89 0.87 0.85 0.89 0.89 0.88 0.84 0.82 0.85 0.86 0.87 0.86 0.87 0.87 0.87 0.87 0.88 0.87 0.85 0.83 0.87 0.87 0.85 0.90 0.83 0.85 0.87 0.86 0.82 0.82 0.78 0.86 0.82 0.81 0.80 0.86 0.83 0.80 0.80 0.81 0.83 0.81 0.82 0.84 0.80 0.78 0.80 0.77 0.80 0.82 0.82 0.81 0.79 0.76 0.77 0.80 0.79 0.81 0.79 0.80 0.76 0.81 0.78 0.77 0.80 0.80 0.77 0.81 0.81 0.81 0.81 0.80 0.79 0.79 0.78 0.81 0.83 0.79 0.74 0.76 0.77 0.79 0.77 0.76 0.77 0.78 0.82 0.75 0.82 0.76 0.70 0.79 0.76 0.76 0.76 0.77 0.74 0.73 0.77 0.75 0.75 0.74 0.76 0.73 0.72 0.73 0.75 0.77 0.73 0.72 0.77 0.72 0.73 0.70 0.76 0.73 0.71 0.72 0.75 0.72 0.73 0.70 0.73 0.75 0.75 0.71 0.75 0.75 0.71 0.70 0.73 0.67 0.74 0.71 0.74 0.70 0.75 0.70 0.72 0.72 0.752007-09-01Comment of the Producer: Ion efficiency curves for the parent negative ions of the three mono-nitrotoluene isomers (m/z=137). Additional Comment: X-Values are measured with an energy resolution of 0.080 eV. Therefore every shown peak is the original peak shape convoluted with our resolution. Energy scans are calibrated. Therefore we estimate an error of 0.1 eVBIDEADB-13elatEDAXIDEADB-111XIDEADB-electronXIDEADB-111Energy of the impact electron0.1Ion Yield331.72 307.07 304.37 270.40 226.86 203.41 181.20 180.44 162.20 145.34 128.71 114.02 102.97 103.20 91.55 83.53 73.77 63.89 52.12 51.72 43.21 35.81 29.68 25.00 25.56 24.36 20.55 20.66 18.37 17.94 16.90 16.95 16.29 15.90 15.09 15.45 14.83 13.78 15.35 14.50 13.32 14.93 15.14 13.78 14.45 13.95 13.02 13.20 13.55 13.73 12.47 13.50 13.61 12.84 12.53 10.71 12.02 13.02 10.85 13.08 11.89 12.47 13.50 12.21 12.34 12.21 11.55 12.53 12.53 11.95 12.84 10.18 11.28 12.34 12.65 11.07 11.07 12.02 11.35 11.75 12.40 12.59 12.21 11.62 11.14 10.85 11.55 12.21 11.35 10.99 12.02 10.78 11.28 11.21 11.75 11.14 10.48 10.71 9.71 10.78 10.48 9.62 10.63 10.18 11.21 11.55 9.71 10.41 9.21 10.63 9.54 10.33 9.79 9.95 9.62 9.46 10.71 9.79 9.62 9.79 8.22 9.79 9.29 9.29 9.12 9.04 9.04 8.12 7.52 8.312007-09-01Comment of the Producer: Ion efficiency curves for the closed shell negative ions (M-H)– formed via loss of a neutral hydrogen atom for the three isomers of mono-nitrotoluene. All anion yields are measured with the monochromator instrument. Additional Comment: X-Values are measured with an energy resolution of 0.080 eV. Therefore every shown peak is the original peak shape convoluted with our resolution. Energy scans are calibrated. Therefore we estimate an error of 0.1 eVBIDEADB-13elatEDAXIDEADB-111XIDEADB-electronXIDEADB-112Energy of the impact electron0.1Ion Yield0.79 0.85 0.86 0.88 0.92 0.95 0.96 0.93 0.93 0.89 0.87 0.77 0.74 0.73 0.77 0.72 0.65 0.55 0.55 0.63 0.69 0.66 0.63 0.58 0.58 0.47 0.41 0.42 0.45 0.40 0.34 0.24 0.12 0.12 0.15 0.02 0.34 0.36 0.38 0.39 0.40 0.40 0.39 0.38 0.36 0.34 0.02 0.16 0.09 0.12 0.22 0.16 0.29 0.07 0.23 0.47 0.42 0.57 0.42 0.20 0.41 0.96 0.88 1.02 1.66 2.04 2.54 2.85 3.24 3.69 4.15 4.72 5.29 5.70 6.17 6.57 7.12 7.55 7.95 8.30 8.65 8.95 9.28 9.55 9.87 10.20 10.44 10.76 10.98 11.16 11.35 11.55 11.70 11.88 11.96 11.80 11.69 11.50 11.28 11.07 10.85 10.48 10.10 9.67 9.27 8.83 8.42 8.01 7.62 7.25 6.84 6.44 6.02 5.79 5.56 5.29 5.03 4.80 4.66 4.55 4.37 4.11 4.02 3.94 3.79 3.70 3.64 3.56 3.54 3.47 3.40 3.27 3.12 3.09 2.96 2.79 2.85 2.80 2.74 2.65 2.61 2.57 2.46 2.42 2.37 2.38 2.43 2.45 2.41 2.51 2.57 2.68 2.82 2.88 2.88 2.89 3.02 3.08 3.14 3.25 3.28 3.29 3.39 3.40 3.49 3.58 3.67 3.83 3.95 3.99 4.09 4.21 4.32 4.46 4.53 4.61 4.62 4.61 4.64 4.69 4.73 4.69 4.68 4.66 4.63 4.56 4.53 4.50 4.53 4.55 4.59 4.63 4.70 4.70 4.73 4.85 4.93 4.99 5.04 5.09 5.13 5.18 5.18 5.19 5.16 5.15 5.18 5.21 5.20 5.08 5.11 5.11 5.12 5.13 5.05 5.05 5.03 4.97 4.95 4.98 4.91 4.87 4.79 4.71 4.62 4.54 4.40 4.37 4.27 4.25 4.18 4.09 3.95 3.81 3.82 3.70 3.62 3.51 3.36 3.37 3.27 3.25 3.17 3.06 3.08 3.01 2.97 3.00 3.04 3.05 3.05 3.11 3.07 3.08 3.00 2.96 2.91 2.83 2.72 2.56 2.49 2.48 2.42 2.34 2.30 2.28 2.15 2.12 2.16 2.16 2.16 2.16 2.16 2.16 2.16 2.16 2.16 2.16 2.16 2.16 2.162007-09-01Comment of the Producer: Ion efficiency curves for the negative ions (M-OH)– formed upon DEA to the three isomers of mono-nitrotoluene. The ion yield for 4-NT is multiplied by 0.15 for better comparison. All anion yields are measured with the monochromator instrument. Additional Comment: X-Values are measured with an energy resolution of 0.080 eV. Therefore every shown peak is the original peak shape convoluted with our resolution. Energy scans are calibrated. Therefore we estimate an error of 0.1 eVBIDEADB-13elatEDAXIDEADB-111XIDEADB-electronXIDEADB-113Energy of the impact electron0.1Ion Yield1.27 0.64 0.64 0.00 0.00 0.90 0.00 0.90 0.00 0.00 0.00 0.00 0.64 0.00 0.00 0.00 0.64 0.64 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.64 0.00 0.64 0.00 0.00 0.00 0.00 0.64 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.64 0.00 0.00 0.00 0.00 0.00 0.64 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.64 0.64 0.00 0.00 0.00 0.00 0.00 0.64 0.64 0.00 0.00 0.00 0.64 0.00 0.00 0.00 0.00 0.00 0.90 1.27 0.00 0.00 1.42 0.64 1.10 1.42 1.91 1.56 1.80 1.56 2.77 2.46 3.18 3.81 4.40 4.67 5.50 6.29 6.25 7.38 8.16 8.06 9.78 10.10 10.43 11.95 12.94 13.91 15.03 15.48 16.49 16.58 17.85 19.18 19.05 21.14 21.40 21.68 22.82 24.04 24.72 25.05 25.89 27.19 27.05 27.86 28.27 30.41 29.99 30.89 32.86 33.56 33.83 34.59 35.89 36.54 37.41 38.57 39.04 39.50 40.53 41.84 41.79 42.03 43.40 43.04 43.18 43.28 44.04 43.44 44.12 43.79 43.13 43.45 43.06 42.25 42.08 41.90 41.61 40.97 40.01 39.12 38.97 37.55 37.73 35.83 35.39 34.44 33.98 32.47 32.06 31.27 29.48 28.99 28.21 27.17 26.37 25.30 24.47 24.13 23.01 21.58 21.08 20.67 19.33 19.63 18.24 17.68 16.80 15.93 15.61 14.51 14.17 13.34 13.08 13.12 12.38 11.52 11.29 11.13 10.78 10.28 10.04 9.29 8.98 9.55 8.80 8.21 8.45 8.33 7.93 7.98 7.59 7.75 7.30 7.75 6.96 6.96 7.16 7.13 6.02 6.81 6.93 6.87 5.96 6.09 6.60 5.89 5.96 5.31 5.75 5.54 5.35 5.85 5.72 4.96 5.57 4.96 5.39 5.27 5.27 5.46 5.04 4.79 5.00 5.46 5.27 5.08 5.39 5.68 4.96 4.62 3.81 4.75 4.53 4.35 4.16 5.04 4.21 4.84 4.62 4.92 4.582007-09-01Comment of the Producer: Ion efficiency curves for the negative ions (M-H2O)– formed upon DEA to the three isomers of mono-nitrotoluene. Additional Comment: X-Values are measured with an energy resolution of 1.000 eV. Therefore every shown peak is the original peak shape convoluted with our resolution. Energy scans are calibrated. Therefore we estimate an error of 0.1 eVBIDEADB-13elatEDAXIDEADB-111XIDEADB-electronXIDEADB-114Energy of the impact electron0.1Ion Yield0.08 0.06 0.09 0.09 0.08 0.09 0.09 0.08 0.07 0.09 0.12 0.07 0.13 0.11 0.13 0.13 0.13 0.14 0.16 0.17 0.17 0.20 0.21 0.22 0.24 0.27 0.32 0.30 0.34 0.36 0.39 0.42 0.46 0.48 0.52 0.54 0.60 0.63 0.69 0.72 0.82 0.86 0.92 0.98 1.06 1.11 1.19 1.28 1.35 1.43 1.53 1.61 1.71 1.80 1.90 1.99 2.10 2.19 2.27 2.38 2.46 2.53 2.61 2.71 2.78 2.87 2.89 2.98 3.03 3.04 3.07 3.13 3.13 3.13 3.16 3.16 3.14 3.12 3.10 3.07 3.01 2.95 2.91 2.86 2.77 2.68 2.60 2.52 2.41 2.34 2.22 2.15 2.05 1.96 1.88 1.79 1.67 1.61 1.49 1.41 1.34 1.26 1.18 1.12 1.05 1.00 0.94 0.91 0.82 0.79 0.74 0.72 0.69 0.64 0.60 0.56 0.54 0.51 0.48 0.47 0.42 0.40 0.40 0.38 0.37 0.35 0.36 0.34 0.34 0.32 0.32 0.31 0.30 0.29 0.28 0.26 0.27 0.28 0.28 0.29 0.28 0.27 0.27 0.27 0.27 0.28 0.25 0.27 0.25 0.26 0.24 0.24 0.26 0.24 0.26 0.22 0.25 0.26 0.23 0.25 0.23 0.23 0.24 0.22 0.23 0.24 0.24 0.23 0.23 0.22 0.22 0.22 0.21 0.23 0.25 0.22 0.23 0.23 0.22 0.23 0.23 0.24 0.21 0.20 0.21 0.24 0.24 0.24 0.23 0.23 0.23 0.23 0.22 0.22 0.24 0.23 0.24 0.23 0.25 0.25 0.23 0.24 0.23 0.24 0.23 0.24 0.23 0.24 0.24 0.22 0.24 0.23 0.23 0.25 0.25 0.23 0.23 0.25 0.24 0.26 0.26 0.25 0.24 0.25 0.27 0.27 0.262007-09-01X-Values are measured with an energy resolution of 0.080 eV. Therefore every shown peak is the original peak shape convoluted with our resolution. Energy scans are calibrated. Therefore we estimate an error of 0.1 eVBIDEADB-13elatEDAXIDEADB-111XIDEADB-electronXIDEADB-115Energy of the impact electron0.1Ion Yield0.00 0.73 0.68 0.63 0.84 1.03 1.03 1.03 1.19 1.19 1.19 1.58 1.58 1.69 1.58 1.69 2.07 2.07 2.53 2.46 2.46 3.04 2.98 3.16 3.48 3.58 4.04 4.04 4.46 4.70 4.62 5.06 5.72 5.87 6.25 6.45 6.90 7.23 7.66 8.50 8.82 9.12 9.61 10.07 10.53 11.17 11.81 12.26 12.71 13.40 14.01 14.39 14.95 15.55 16.02 16.79 17.46 17.73 18.41 18.70 19.37 19.77 20.34 20.62 20.83 21.27 21.88 22.26 22.89 23.32 23.71 24.07 24.41 24.63 24.82 25.09 25.07 25.14 25.49 25.81 25.78 26.05 26.41 26.63 26.87 27.38 27.55 27.69 27.89 28.23 28.50 28.46 28.62 28.55 28.68 28.96 28.99 29.06 29.22 29.42 29.74 29.89 30.20 30.37 30.30 30.50 30.66 30.68 30.75 30.89 30.97 30.74 30.72 30.77 31.11 31.14 31.05 30.81 30.53 30.56 30.77 30.54 30.70 30.57 30.49 30.42 30.55 30.68 30.40 30.32 30.49 30.11 29.66 29.43 29.00 28.60 28.17 28.06 27.74 27.08 26.75 26.54 26.07 25.72 25.45 24.97 24.57 24.24 24.01 23.89 23.64 23.48 23.17 22.54 22.26 21.56 21.00 20.26 19.79 19.29 18.78 18.23 18.09 17.85 17.81 17.54 17.51 17.13 16.60 16.28 16.21 15.85 15.51 15.04 14.57 14.16 13.64 13.49 13.15 12.79 12.38 12.13 11.91 11.68 11.45 11.36 11.08 10.99 10.83 10.63 10.38 10.33 10.05 9.96 9.92 9.78 9.54 9.27 8.88 8.53 8.00 7.48 7.21 6.40 6.93 6.24 6.86 5.66 4.58 5.74 5.20 5.29 4.36 3.74 3.46 3.46 3.46 3.46 3.46 3.46 3.46 3.46 3.46 3.46 3.462007-09-01X-Values are measured with an energy resolution of 0.080 eV. Therefore every shown peak is the original peak shape convoluted with our resolution. Energy scans are calibrated. Therefore we estimate an error of 0.1 eVBIDEADB-13elatEDAXIDEADB-111XIDEADB-electronXIDEADB-116Energy of the impact electron0.1Ion Yield0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 1.00 0.00 0.00 0.00 0.00 1.00 0.00 0.00 1.00 1.41 1.41 1.41 1.41 2.00 1.41 1.00 1.73 1.41 2.65 4.12 3.46 3.46 4.24 4.24 4.00 4.69 6.32 5.20 6.08 7.07 7.28 8.54 8.60 8.25 9.43 10.30 10.72 10.72 11.36 12.25 13.45 13.08 13.64 15.17 15.33 15.07 15.36 15.56 16.34 16.55 16.49 18.08 17.44 17.44 17.78 17.61 18.11 18.03 18.33 18.41 18.14 18.49 18.57 18.97 17.80 18.76 17.58 17.66 18.17 18.11 17.72 17.38 17.29 17.23 16.94 17.18 16.91 15.94 15.20 16.25 15.20 15.46 15.26 15.07 14.28 14.56 14.66 13.15 13.00 13.49 12.69 12.96 12.57 12.45 12.49 11.05 10.49 10.10 9.85 9.75 9.27 9.17 8.37 7.87 7.68 7.62 8.12 6.00 7.14 7.75 6.71 6.63 5.29 5.39 6.32 5.48 5.00 4.80 5.48 5.20 5.29 5.00 4.12 4.58 3.74 5.20 3.32 4.47 3.16 2.65 3.16 3.74 3.74 3.87 4.12 3.74 3.87 3.87 4.12 3.74 3.74 3.74 3.74 4.36 4.00 3.32 3.87 2.83 4.36 3.46 3.46 3.46 3.61 4.12 4.12 3.46 3.46 3.46 4.12 3.61 3.00 3.32 3.74 3.61 3.74 4.80 3.61 3.46 3.87 4.00 3.87 4.00 3.00 4.36 5.20 3.74 4.47 4.00 3.74 4.00 4.47 4.36 4.00 3.87 4.00 3.87 4.47 4.00 4.00 3.87 3.00 4.12 3.87 3.74 3.61 2.83 4.12 3.46 3.16 3.87 2.45 3.00 3.46 4.24 2.65 2.45 3.32 3.16 3.32 2.65 3.46 2.65 2.65 3.32 3.46 2.65 4.00 3.00 3.16 3.74 4.24 2.83 3.46 4.00 2.65 3.74 2.83 3.32 3.16 3.87 3.16 3.61 3.46 3.32 3.16 4.12 3.00 3.87 3.00 3.74 3.00 3.46 3.61 3.87 2.24 2.24 3.46 2.65 2.83 3.00 3.32 3.87 3.46 3.16 2.83 2.45 2.83 3.61 2.65 3.32 3.46 2.83 3.32 2.83 3.00 1.73 3.74 3.00 2.24 2.45 2.65 3.16 3.00 2.00 3.46 2.45 1.41 1.41 1.00 2.24 2.45 1.73 2.00 2.002007-09-01Comment of the Producer: The abundance of (M-NO2)– is about five times higher for 2-NT compared to the other isomers and for better comparison multiplied with a factor of 0.25. Additional Comment: X-Values are measured with an energy resolution of 0.080 eV. Therefore every shown peak is the original peak shape convoluted with our resolution. Energy scans are calibrated. Therefore we estimate an error of 0.1 eVBIDEADB-13elatEDAXIDEADB-111XIDEADB-electronXIDEADB-117Energy of the impact electron0.1Ion Yield0.00 1.73 1.00 1.41 1.41 1.41 1.41 1.73 0.00 1.41 0.00 1.73 2.00 1.41 1.41 1.73 0.00 0.00 1.41 1.00 1.41 1.41 0.00 2.00 0.00 2.00 0.00 1.41 0.00 1.00 1.41 1.73 0.00 0.00 1.73 1.41 0.00 1.00 1.41 2.00 0.00 0.00 1.00 1.73 1.00 1.00 2.45 2.00 2.65 2.45 2.83 3.16 3.00 3.74 3.32 3.87 4.36 5.00 4.24 5.00 5.20 4.80 6.63 6.08 6.93 6.48 6.93 6.93 8.43 8.12 8.25 9.22 10.10 9.22 10.25 10.39 10.25 11.05 10.95 11.53 11.96 12.41 12.45 12.53 13.30 13.53 14.04 14.00 14.63 14.46 15.33 14.25 14.42 14.83 14.83 15.36 15.59 14.80 16.22 15.43 15.20 15.13 15.26 14.66 15.17 14.53 14.73 14.63 14.21 14.76 13.89 13.45 13.93 13.27 13.04 12.81 11.58 13.67 12.08 11.27 11.14 11.96 12.04 10.72 9.22 10.54 9.75 9.59 10.10 8.89 9.80 9.90 9.33 8.43 7.94 7.94 8.31 7.68 7.62 8.54 7.75 6.78 7.75 6.40 6.40 8.25 7.68 6.40 7.55 7.00 7.07 7.28 7.55 7.75 8.06 7.94 8.89 8.25 8.89 9.17 9.33 9.80 10.30 9.49 10.10 10.68 10.72 11.18 11.96 12.77 12.08 12.49 13.30 14.66 13.86 14.07 14.46 14.76 14.53 15.33 14.59 15.13 15.65 16.37 15.39 16.09 16.28 16.88 16.52 16.58 16.03 15.26 15.33 15.94 15.20 16.31 16.28 15.52 15.00 15.52 14.90 14.63 14.49 13.82 14.28 13.75 13.19 13.60 13.30 12.25 11.27 12.85 11.62 11.22 10.91 11.62 11.14 10.49 9.75 9.06 9.64 8.77 8.94 7.94 8.37 7.42 7.94 7.48 7.42 6.63 6.48 6.16 7.81 6.71 5.39 6.08 6.08 6.40 5.48 7.00 6.32 6.00 5.66 4.80 6.71 5.48 5.48 5.10 6.32 6.56 6.48 5.57 5.00 5.92 5.00 5.10 5.66 6.24 6.16 5.66 5.10 6.48 5.29 6.08 6.00 5.74 5.20 4.90 5.48 5.10 5.83 5.48 5.10 5.83 5.57 5.83 5.66 5.57 4.90 4.80 5.74 5.66 5.00 5.00 4.47 6.08 4.69 4.80 4.12 4.47 4.47 5.66 4.80 4.00 3.16 3.61 4.24 4.47 4.47 4.362007-09-01Comment of the Producer: For mass m/z=88 only for 2-NT the monochromator instrument is utilized (thin solid line). For better comparison the anion efficiency curve for this anion formed upon DEA to 4-NT is multiplied with a factor of 10. Additional Comment: X-Values are measured with an energy resolution of 1.000 eV. Therefore every shown peak is the original peak shape convoluted with our resolution. Energy scans are calibrated. Therefore we estimate an error of 0.1 eVBIDEADB-13elatEDAXIDEADB-111XIDEADB-electronXIDEADB-118Energy of the impact electron0.1Ion Yield0.00 0.03 0.00 0.04 0.00 0.00 0.00 0.03 0.00 0.04 0.03 0.03 0.03 0.03 0.00 0.03 0.03 0.00 0.00 0.00 0.00 0.05 0.03 0.05 0.05 0.04 0.04 0.06 0.08 0.05 0.06 0.06 0.09 0.09 0.09 0.10 0.14 0.11 0.13 0.13 0.16 0.16 0.15 0.18 0.21 0.22 0.23 0.23 0.27 0.27 0.29 0.33 0.32 0.36 0.38 0.35 0.39 0.35 0.37 0.42 0.45 0.49 0.52 0.54 0.58 0.63 0.67 0.77 0.80 0.88 0.92 0.98 1.01 1.07 1.12 1.20 1.24 1.32 1.35 1.40 1.46 1.52 1.57 1.59 1.61 1.66 1.71 1.70 1.71 1.72 1.73 1.73 1.72 1.73 1.69 1.64 1.64 1.62 1.58 1.53 1.52 1.46 1.43 1.40 1.35 1.29 1.25 1.20 1.17 1.13 1.08 1.05 1.02 1.00 0.96 0.94 0.91 0.85 0.86 0.82 0.82 0.80 0.78 0.77 0.76 0.75 0.76 0.76 0.77 0.71 0.71 0.73 0.74 0.73 0.71 0.76 0.75 0.74 0.75 0.77 0.78 0.76 0.72 0.74 0.74 0.75 0.74 0.75 0.73 0.74 0.71 0.72 0.72 0.70 0.71 0.70 0.70 0.68 0.69 0.70 0.67 0.67 0.66 0.66 0.66 0.66 0.62 0.66 0.65 0.67 0.64 0.67 0.64 0.63 0.64 0.59 0.64 0.62 0.64 0.63 0.62 0.63 0.62 0.63 0.60 0.60 0.59 0.59 0.58 0.60 0.61 0.56 0.59 0.57 0.57 0.57 0.56 0.56 0.54 0.56 0.55 0.55 0.54 0.53 0.54 0.54 0.52 0.52 0.51 0.53 0.53 0.52 0.51 0.49 0.50 0.50 0.47 0.49 0.49 0.45 0.50 0.46 0.47 0.47 0.44 0.48 0.45 0.44 0.46 0.44 0.45 0.48 0.48 0.46 0.47 0.46 0.45 0.48 0.47 0.48 0.46 0.45 0.41 0.47 0.44 0.45 0.44 0.41 0.43 0.44 0.45 0.46 0.43 0.47 0.42 0.44 0.47 0.44 0.46 0.45 0.46 0.46 0.45 0.46 0.45 0.44 0.41 0.39 0.46 0.44 0.42 0.44 0.45 0.45 0.42 0.42 0.40 0.44 0.43 0.45 0.42 0.42 0.41 0.41 0.44 0.41 0.40 0.42 0.41 0.42 0.41 0.42 0.41 0.43 0.39 0.43 0.412007-09-01X-Values are measured with an energy resolution of 1.000 eV. Therefore every shown peak is the original peak shape convoluted with our resolution. Energy scans are calibrated. Therefore we estimate an error of 0.1 eVBIDEADB-13elatEDAXIDEADB-111XIDEADB-electronXIDEADB-119Energy of the impact electron0.1Ion Yield0.06 0.00 0.06 0.00 0.00 0.00 0.06 0.00 0.10 0.06 0.00 0.00 0.10 0.00 0.06 0.06 0.00 0.10 0.06 0.00 0.08 0.10 0.08 0.00 0.10 0.00 0.00 0.12 0.12 0.15 0.15 0.13 0.15 0.15 0.16 0.19 0.20 0.18 0.22 0.25 0.28 0.22 0.23 0.25 0.35 0.35 0.31 0.33 0.45 0.42 0.46 0.45 0.48 0.55 0.61 0.69 0.62 0.70 0.74 0.79 0.80 0.86 0.94 1.00 1.07 1.11 1.17 1.11 1.26 1.27 1.37 1.37 1.46 1.48 1.52 1.58 1.68 1.70 1.75 1.73 1.82 1.96 1.96 1.98 2.08 2.19 2.21 2.24 2.39 2.35 2.42 2.45 2.57 2.56 2.58 2.62 2.77 2.73 2.83 2.90 2.89 2.87 2.97 2.94 3.00 2.98 3.03 3.06 3.07 3.13 3.12 3.12 3.16 3.08 3.13 3.09 3.12 3.12 3.14 3.10 3.13 3.08 3.03 3.11 3.01 2.99 2.99 2.94 2.89 2.88 2.89 2.84 2.80 2.76 2.72 2.68 2.66 2.56 2.57 2.52 2.48 2.51 2.47 2.46 2.46 2.41 2.41 2.45 2.28 2.40 2.41 2.37 2.36 2.32 2.38 2.34 2.34 2.37 2.38 2.38 2.40 2.37 2.36 2.39 2.42 2.46 2.46 2.57 2.48 2.48 2.51 2.51 2.48 2.58 2.50 2.54 2.50 2.44 2.50 2.44 2.49 2.44 2.46 2.43 2.45 2.36 2.38 2.35 2.31 2.30 2.29 2.24 2.23 2.16 2.18 2.14 2.13 2.04 2.03 2.04 1.96 1.96 1.96 1.87 1.85 1.85 1.82 1.86 1.74 1.72 1.68 1.69 1.61 1.66 1.61 1.59 1.62 1.56 1.65 1.56 1.59 1.57 1.53 1.61 1.59 1.64 1.53 1.51 1.55 1.58 1.58 1.56 1.55 1.53 1.58 1.52 1.55 1.51 1.54 1.53 1.56 1.57 1.50 1.54 1.51 1.55 1.49 1.52 1.46 1.50 1.52 1.52 1.51 1.48 1.42 1.49 1.38 1.40 1.42 1.42 1.40 1.37 1.32 1.39 1.35 1.34 1.28 1.34 1.28 1.33 1.32 1.28 1.20 1.25 1.27 1.25 1.17 1.18 1.15 1.21 1.20 1.18 1.18 1.15 1.14 1.17 1.15 1.12 1.11 1.14 1.11 1.132007-09-01